报告题目：Magnetic dipole and quadrupole transition moments for the known spectral bands of N2 molecule and predictions of new emission in visible region.

报告人：Professor Boris F. Minaev

报告时间： 10月3日14:30

ZOOM会议：ID：848 5105 2714   密码：082525

主持人：闫冰教授

主办单位：吉林大学原子与分子物理研究所

报告摘要：

We summarize the previous lecture by comparison with experiment singlet-triplet transitions in N2: Vegard-Kaplan, Wu-Benesh and Ogawa-Tanaka-Wilkinson bands systems, which are induced by spin-orbit coupling (SOC) as electric-dipole emission and absorption. Than, the magnetic dipole transition moments are  calculated and analyzed for the first time in our new lecture: the weak Wilkinson absorption, the Lyman-Berge-Hopfield 0–0 band a1Πg←X1Σg+ in absorption with oscillator strength f0–0=7.24˟10–6. The growth of magnetic strength of the a1Πg→X1Σg+ transition and the decrease of its quadrupole moment with internuclear distance are notable. We shall also estimate a new quadrupole transition a1Πg→B3Πg,1. Accounting for SOC, this transition moment  origins in difference in the permanent quadrupole moments of these two states. Finally, the Dressler-Lutz a"1Σg+–X1Σg+quadrupole transition in the far UV absorption region (101 nm) with peculiar anisotropy will be calculated.

报告人简介:

Boris F. Minaev is the head of Chemistry and Nanomaterial Science Department at the Bohdan Khmelnytsky National University in Cherkasy, Ukraine.He was awarded the Honored Worker of Science and Technology of Ukraine on 2012. He was awarded Life achievements award from American Biographic Institute for “The Singlet Oxygen Emission Theory”on 1999. He is the leader and coordinator of national research projects: a number of projects (five) in organic synthesis and electronic structure calculations for development of OLED technology (2008-2021) governed by Ministry of Education and Science in Ukraine.